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Virginia "Pepper" Potts was originally in the secretarial pool at Stark Industries. She is promoted to Tony Stark's personal assistant after fixing an accounting mistake made by Stark himself. She is never addressed to as Virginia, but only by her nickname. At times she is virtually the only real friend he has at the company.
When Tony believes he going to die of the palladium in the reactor, he promotes Pepper to CEO of Stark Industries. Once Tony finds a cure, however, she resigns. In The Avengers she has become his lover and partner.
[Disclaimer: Not really Pepper Potts (I wish man) who belongs to Marvel entertainment. This Pepper is set post-Avengers but I will not force any Tony Starks I come across into playing the romantic relationship unless they want to. Gwyneth Paltrow belongs to herself. No copyright infringement intended. Muse and Mun are over 21.]